Reem A. A. Al-Qattan; Qahtan Al-Khafagi
Volume 23, Issue 3 , September 2023, , Pages 147-157
Abstract
Abstract
The study included two sites for two soils of different textures (Al-Mazara and Bashiqa) within Nineveh Governorate - Iraq. Soil samples were taken from the surface depth (30 cm) naturally by means of columns. The experiment was carried out by adding two types of water (river water and well ...
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Abstract
The study included two sites for two soils of different textures (Al-Mazara and Bashiqa) within Nineveh Governorate - Iraq. Soil samples were taken from the surface depth (30 cm) naturally by means of columns. The experiment was carried out by adding two types of water (river water and well water) to each column with a volume equivalent to The pore size, and alternating wetting and drying were done for ten cycles, and the period between one cycle and another was 10 days. Soil samples were analyzed after the first cycle, the fifth cycle, and the tenth cycle to find out the effect of the number of humidification cycles on the exchanged ions, the relative effectiveness, and the Gapon constant. The results indicated that the released amount of exchanged calcium ions in the soil of Bashiqa was higher than the amount released in the soil of the Al-Mazara, while the amount of magnesium ions released in the soil of Al-Mazara was higher than the amount released in the soil of Bashiqa and when using both types of water, while the relative effectiveness values for calcium, the values were higher when wetting with well water, except for the first cycle in the soil of Al-Mazara and the tenth cycle in the soil of Al-Mazara and Bashiqa, while the relative effectiveness of magnesium in the two study soils, the values were higher when wetting with well water and for all cycles except the fifth cycle in Bashiqa soil, while the Gapon constant for calcium in the two study soils had higher values when wetting with river water in the fifth cycles, while in the first and tenth cycles the values were higher when wetting with well water, except for the first cycle in Bashiqa soil, while the Gapon constant for magnesium in the two study soils, the values were higher when wetting with well water and for all cycles except for the first and fifth cycle in Al-Mazara soil. Then the following kinetic equations were applied: zero order equation, first order equation, diffusion equation, Eluvich equation and power function equation, the power function equation was the best equation that describes the process of release calcium and magnesium ions in the study soil.
Nameer Hamed Yassin Al-Tarbouli
Volume 22, Issue 3 , September 2022, , Pages 137-147
Abstract
Three soils of different content of gypsum and lime were selected, the first soil (G1) and the second soil (G3), were obtained near the fields of the Faculty of Agriculture, Tikrit University. As for the third soil (G5), was taken from the AL- alam Village side east of Tikrit city to a depth of (0-10)cm. ...
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Three soils of different content of gypsum and lime were selected, the first soil (G1) and the second soil (G3), were obtained near the fields of the Faculty of Agriculture, Tikrit University. As for the third soil (G5), was taken from the AL- alam Village side east of Tikrit city to a depth of (0-10)cm. the proportions of gypsum were 5%, 15%, 25%, and the proportions of lime were 25%, 20%, and 10% for soils G1, G3, and G5, respectively. Ferrous sulfate was added as a source of iron ions added to the three soils in the following proportions (0,10,25,50,100,150,250,500,750) mg.L-1 The concepts of isotherm were tested by using the physicochemical Freundlich and Langmuir adsorption equations. The results of the study showed the success of both equations in describing of iron ion adsorption process for all three soils, because They achieve a high (R2) but Langmuir's equation showed a greater superiority due to its decreasing (SE). As it appears from the results of the study, the superiority of treatment (G1) over treatments (G3) and (G5) in the maximum adsorption values, binding energy, (PBCFe)(KG) and (Kd) for adsorption and release. As for the values of Labale iron, the lowest value was in treatment (G1)then it began to increase until it reached its value in treatment (G5). The (Δf) values for the three soils were positive, and that the highest value was in soil (G1), and starts declining to reach its value for soil (G5).
